Thus, neem oil as nonedible oil can be a good renewable raw material for biodiesel production. Neem oil will become a potential supplier of biodiesel in future. These values clearly indicate that the use of neem oil methyl esters in colder regions is limited. Juss oil by its basecatalyzed transesterification and its blending with diesel. However, its relatively high free fatty acid content is a major drawback, which leads to a low yield of biodiesel, evaluated on average at 89.
The goal of this lca study was to assess the sustainability of biodiesel production form neem oil, for different life cycle stages and the overall life cycle under. This was with a view to establish its production and viability potentials. Neem seed oil has been used in the production of biodiesel but with a two step free fatty acid content reduction. Biodiesel production from neem seeds azadirachta indica.
This bio diesel contains alkyl esters of the fatty acids which is the product of the transesterification process of the neem oil. However, the blending of the oil with diesel is also used. Rice bran is a coproduct of rice milling, containing about 1523% oil sinha et al. The conventional 2step transesterification production of biodiesel using sulphuric acid and potassium hydroxide as catalysts is carried out. At maturity, the neem tree can produce up to 50 kg of fruits per year, equivalent to 30 kg of seeds per year 7.
This solventextracted oil is of a lower quality as compared to the cold pressed oil and is mostly used for soap manufacturing. Due to large population and the need of transportation made india. Thus, rapeseed and sunflower oils are principally used in europe for biodiesel production, palm oil predominates in tropical countries, and. Because of the increasing edible oil prices, it is not viable to produce biodiesel from edible oils. It also contains polyunsaturated fatty acids such as oleic acid and linoleic acids. Neem, being recalcitrant and crosspollinating in nature, is. The economic evaluation has also shown that the biodiesel production from neem is very profitable. The neem biodiesel system was assessed using lca method according to the international organization for standardization procedures iso 1401044. Neem oil is proved to contain methyl ester which is considered to be the base of a bio diesel. New process for the production of biodiesel from neem oil. A large industry in india extracts the oil remaining in the seed cake using hexane. Sekhar and others published production of biodiesel from neem oil find, read and cite all the research you need. But till now, heterogeneous chemical catalysts are used to convert the neem oil to biodiesel.
This report deals with biodiesel obtained from neem oil which are mono alkyl esters produced using transesterification process. Generally, the most abundant commodity oils or fats in a particular region are the most common feedstocks. Studies on optimization of transesterification of certain. Neem seed oil have also been utilized as biodiesel production sekhar et al. Biodiesel from neem oil as an alternative fuel for a diesel engine. Biofuel is an alternative and environment friendly source of energy, originated by the use of fossil fuels and have led to a notable growing demand from the last few decades. Production of biodiesel from crude neem oil feedstock and its. Optimization of twostep transesterification production of biodiesel from neem azadirachta indica oil, international journal of energy and environmental engineering, 20, pp. Studies on optimization of transesterification of certain oils to produce biodiesel. Pdf production of biodiesel from neem seed oil researchgate.
Juss seeds oil nso, a nonedible oil available in large quantities in senegal may be a second generation feedstock for biofuel production. Chemistry international 22 2016 5969 introduction india occupies second place in population and 7th place in area in the world oil production abolle et al. Coconut and neem biodiesel as an alternative to fossil diesel. Page 3 of 10 which is greatly available in rice cultivating countries. Biodiesel production from neem seeds azadirachta indica a. Due to its high acid value, the neem oil was processed. The objective of this work therefore is to report the lipozyme tl im catalyzed transesterification yields for biodiesel production from neem, shea and mango oils. This study looks at the effect of various methanol quantities on acid concentration on reduction of free fatty acid content in neem seed oil having acid value of 29. This study investigates biodiesel production using crude neem oil having high acid value, as a feedstock. Characteristics and comparison of diesel fuel and biodiesel. Esolventfree, enzymecatalyzed biodiesel production from. Neem oil is generally light to dark brown, bitter and has a rather strong odour that is said to combine the odours of peanut and garlic. Production of biofuel from crude neem oil and its performance. Biodiesel production from seed oils of neem and pongamia was investigated using base catalyzed transesterifiction process.
Particularly neem oil has tickled the researchers for its use in the production of the biofuel. Low cost and abundantly found nonedible oils such as neem oil could be a better option for biodiesel processing. Primarily, biodiesel is produced from food crops and mostly oil seeds which are limited in their ability to achieve targets for replacement of fossil diesel, climate change and economic mitigation and their competition with the food has lead to the focus on microalgae which offer a better and reliable source for biodiesel production. Biodiesel production is a valuable process which needs a continued study and. This paper deals with biodiesel production from neem oil, which is monoester produced using transesterification process. Therefore, ffas were first transformed to esters in a pretreatment process using h 2 so 4 catalyst to reduce the acid. The triglycerides transesterification is the most used process in the biodiesel production. Current strategies and prospects of biodiesel production. Physicochemical properties of biodiesel produced from neem oil. The aim of this study is to investigate the production of biodiesel from neem oil and to characterize the parameters that affect biodiesel performance. Pdf biodiesel production from neem seed azadirachta indica. Pdf p neem oil was extracted from neem seeds by mechanical extraction method. A novel method applied to the production of biodiesel from.
Biodiesel is a mono alkyl ester produced through transesterification processes. Functional properties of neem oil as potential feedstock for. The variables affecting the yield and characteristics of the biodiesel made were studied. Production and characterization of neem oil methyl ester. Neem oil is nonedible oil and it is an effective alternative source for the production of biodiesel. Production of biodiesel from sunflower oil and ethanol by. Pdf pneem oil was extracted from neem seeds by mechanical extraction method. Pretreatment of the tallow or oil feedstock to remove components that will be detrimental to subsequent processing steps. Therefore using this neem biodiesel alone in diesel engines could cause poor atomization of the fuel upon injection into the cylinder, deposit formation, clogging of fuel pumps and carbon build up. Various sources for production of biodiesel pathak et al.
As biodiesel are usually acquired from renewable sources like vegetable and. Biodiesel from neem oil as an alternative fuel for diesel. Production of biofuel from crude neem oil and its performance 427 1. When 1 liter 900g of the neem oil was subjected to the above process, the yield of free fatty acid was 855. Production, characterization and process variables of.
Pdf production of biodiesel from neem oil researchgate. Biodiesel can be produced from neem seeds vegetable oils using transesterification process, which is the reaction of the neem seeds oil with alcohol methanol to form neem oil methyl ester nome and glycerol as byproduct. Biodiesel production from neem oil an alternate approach. The theoretical maximum amount 100% of free fatty acid that can be produced from 900g of neem. Neem oil had a very high initial acid value of 34 mg kohg corresponding to a ffa level of 17%. Neem oil can also be obtained from solvent extraction of the neem seed, fruit, oilcake or kernel. Here, we focused on the higher production of biodiesel from neem oil using microbial lipase as a. Process optimization of biodiesel production from neem oil. The present study was intended to consider aspects related. Biodiesel, in general, and from neem oil in particular, involves conversion of these long and branched chain triglyceride molecules to its methyl esters. The unrefined crude neem oil is dark brown in colour. The capital investment for a sebp plant ranges between r110 and r145 million while a cobp plant would require a capital investment of about r45 to r50 million. The effects of some operating variables were ascertained and its combustion performance was assessed in an internal combustion engine.
The oil content varies from 30 to 52% for the kernels and from 20 to 32% for the seeds 8,9. The present study was intended to consider aspects related to the production of biodiesel from neem oil and investigating its fuel properties. Nov 14, 20 this work investigated the optimization of biodiesel production from neem azadirachta indica oil using a twostep transesterification process and determination of the qualities of the neem oil biodiesel. Feedstocks for biodiesel production vary with location according to climate and availability. However, such studies are limited in neem oil which thus warrants systematic investigation. In this study, neem oil which is one of the abundant nonedible oils in india, nepal, pakistan, sri lanka and bangladesh is used for biodiesel production. The chemical basis of vegetable oils, regardless of their origins, is triglyceride, which consists of glycerol and three carboxylic or fatty acids 1, 33. Neem oil contains four significant saturated fatty acids, of which two are palmitic acid and two are stearic acid. The obtained results were analyzed and compared with conventional diesel fuels. Pdf production and characterization of biodiesel from. This study also reveals that neem oil, by its physicochemical characteristics, has a satisfactory quality for a valorization in the production of biodiesel.
The optimum conditions to achieve maximum yield of biodiesel were investigated at different temperatures and with different molar ratio of neem oil and methanol. Biodiesel production is a valuable process which needs a continued study and optimization process. Influence of physicochemical characteristics of neem seeds. Neem tree is evergreen tree growing in almost every state of fndia. This two step process gave maximum average yield of 902%.
Biodiesel production using neem oil with lipase from. Production of biodiesel from highffa neem oil and its performance, emission and combustion characterization in a single cylinder dici engine. Furthermore, neem oil biodiesel has a pour point of 40c and a cloud point of 20c. Production and characterization of biodiesel from jatropha oil and neem oil. The flash point of the neem oil biodiesel produced was 153. Biodiesel production from neem seed azadirachta indica oil. Optimization of twostep transesterification production of. Biodiesel from neem oil as an alternative fuel for diesel engine.